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Accessibility information
Author(s):   Rubin, R.; Persky, a.
Title:   Kinetic study of the reaction of atomic chlorine with hydrogen bromide
Journal:   J. Chem. Phys.
Volume:   79
Year:   1983
Reference type:   Journal article
Squib:   1983RUB/PER4310

Reaction:   HBr + ·ClHCl + Br·
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Temperature:   222 - 504 K
Pressure:  5.33E-4 - 6.67E-4 bar
Rate expression:   4.8x10-11 [cm3/molecule s] e-3775 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
222 6.21E-12
225 6.38E-12
250 7.81E-12
275 9.21E-12
300 1.06E-11
325 1.19E-11
350 1.31E-11
375 1.43E-11
400 1.54E-11
425 1.65E-11
450 1.75E-11
475 1.85E-11
500 1.94E-11
504 1.95E-11