NIST Chemical Kinetics Database

Author(s):   Madden, L.K.; Moskaleva, L.V.; Kristyan, S.; Lin, M.C.
Title:   Ab initio MO study of the unimolecular decomposition of the phenyl radical
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   6790 - 6797
Year:   1997
Reference type:   Journal article
Squib:   1997MAD/MOS6790-6797

Reaction:   Phenyl → Other Products + H·
Reaction order:   1
Temperature:   700 - 2500 K
Pressure:  1.01 bar
Rate expression:   7.66x10³³ [s^-1] (T/298 K)^-16.00 e^{-534621 [J/mole]/RT}
Bath gas:   Ar
Category: Experiment
Data type:   RRK(M) extrapolation

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
700	1.14E-12
800	1.31E-8
900	1.50E-5
1000	3.52E-3
1100	2.65E-1
1200	8.59E0
1300	1.47E2
1400	1.54E3
1500	1.09E4
1600	5.66E4
1700	2.28E5
1800	7.47E5
1900	2.06E6
2000	4.93E6
2100	1.04E7
2200	1.99E7
2300	3.49E7
2400	5.66E7
2500	8.60E7