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Title: Kinetics of the thermolysis of [n.2.2]propellanes and related compounds. Mechanism of the thermolysis of bicyclo[2.2.0]hexanes
Journal: J. Am. Chem. Soc.
Volume: 112
Page(s): 5854 - 5861
Year: 1990
Reference type: Journal article
Squib: 1990WIB/CAR5854-5861
Reaction:
Tetracyclo[4.2.1.1.2,50.2,6]undec-3-ene → Bicyclo[4.2.1]non-7-ene,2,5-bis(methylene)-
Reaction order:
1
Temperature:
523 - 582
K
Rate expression:
1.58x1014 [s-1] e-172941 [±3467 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 523 | 8.44E-4 |
| 525 | 9.82E-4 |
| 550 | 5.95E-3 |
| 575 | 3.08E-2 |
| 582 | 4.76E-2 |