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Title: Phenyl radical plus propene: a prototypical reaction surface for aromatic-catalyzed 1,2-hydrogen-migration and subsequent resonance-stabilized radical formation
Journal: Phys. Chem. Chem. Phys.
Volume: 20
Page(s): 13191 - 13214
Year: 2018
Reference type: Journal article
Squib: 2018BUR/CHU13191-13214
Reaction:
CH3CH=CH2 + Phenyl → Products
Reaction order:
2
Temperature:
300 - 700
K
Pressure: 1.33E-2 - 3.33E-2 bar
Rate expression:
no rate data available
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
Experimental values of the rate constant are given in tabular and graphical formats. No Arrhenius expression is provided.
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