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Author(s):   Buras, Z.J.; Chu, T.-C.; Jamal, A.; Yee, N.W.; Middaugh, J.E.; Green, W.H.
Title:   Phenyl radical plus propene: a prototypical reaction surface for aromatic-catalyzed 1,2-hydrogen-migration and subsequent resonance-stabilized radical formation
Journal:   Phys. Chem. Chem. Phys.
Volume:   20
Page(s):   13191 - 13214
Year:   2018
Reference type:   Journal article
Squib:   2018BUR/CHU13191-13214

Reaction:   CH3CH=CH2 + Phenyl → Products
Reaction order:   2
Temperature:   300 - 700 K
Pressure:  1.33E-2 - 3.33E-2 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Experimental values of the rate constant are given in tabular and graphical formats. No Arrhenius expression is provided.

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