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Title: Very low pressure pyrolysis. II. Decomposition of nitropropanes
Journal: J. Am. Chem. Soc.
Volume: 89
Page(s): 6030 - 6035
Year: 1967
Reference type: Journal article
Squib: 1967SPO/BEN6030-6035
Reaction:
C2H5NO2 → C2H4 + HNO2
Reaction order:
1
Temperature:
667 - 769
K
Rate expression:
5.6x1011 [s-1] e-179593 [±8980 J/mole]/RT
Uncertainty:
5.0
Bath gas:
C2H5NO2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 667 | 4.83E-3 |
| 675 | 7.09E-3 |
| 700 | 2.22E-2 |
| 725 | 6.44E-2 |
| 750 | 1.74E-1 |
| 769 | 3.54E-1 |