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Title: Rate coefficients for cycloalkyl plus O reactions and product branching in the decomposition of chemically activated cycloalkoxy radicals: an experimental and theoretical study
Journal: Phys. Chem. Chem. Phys.
Volume: 12
Page(s): 8954 - 8968
Year: 2010
Reference type: Journal article
Squib: 2010HOY/MAA8954-8968
Reaction:
Cyclohexyl + O· → Cyclohexanone + H·
Reaction order:
2
Reference reaction:
Cyclohexyl + O· → Products
Reference reaction order:
2
Temperature:
298
K
Pressure: 4.00E-3 - 1.00 bar
Rate expression:
2.4x10-1
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
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