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Title: Gas-phase rate coefficients for the reactions of nitrate radicals with (Z)-pent-2-ene, (E)-pent-2-ene, (Z)-hex-2-ene, (E)-hex-2-ene, (Z)-hex-3-ene, (E)-hex-3-ene and (E)-3-methylpent-2-ene at room temperature
Journal: Phys. Chem. Chem. Phys.
Volume: 7
Page(s): 2506 - 2512
Year: 2005
Reference type: Journal article
Squib: 2005PFR/MAR2506-2512
Reaction:
(Z)-2-C6H12 + NO3 → Products
Reaction order:
2
Reference reaction:
(E)-2-C4H8 + NO3 → Products
Reference reaction order:
2
Temperature:
300
K
Pressure: 1.01 bar
Rate expression:
1.4±1.8x10-1
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
NMO3 obtained by the thermal decomposition of N2O5
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