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Title: Excited chloroethyl radicals C2H2Cl5-x
Journal: Proc. Chem. Soc. London
Page(s):
Year: 1961
Reference type: Journal article
Squib: 1961AYS/COC244
Reaction:
C2HCl3 + ·Cl → CHCl2C(·)Cl2
Reaction order:
2
Temperature:
298 - 423
K
Pressure: 6.67E-2 bar
Rate expression:
6.61x10-12 [cm3/molecule s] e-2927 [J/mole]/RT
Bath gas:
Cl2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 2.03E-12 |
| 300 | 2.04E-12 |
| 325 | 2.24E-12 |
| 350 | 2.42E-12 |
| 375 | 2.59E-12 |
| 400 | 2.74E-12 |
| 423 | 2.88E-12 |