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Title: FTIR Study of the Cl- and Br-Atom Initiated Oxidation of Trichloroethylene
Journal: Int J. Chem. Kinet.
Volume: 29
Page(s): 695 - 704
Year: 1997
Reference type: Journal article
Squib: 1997CAT/ARI695-704
Reaction:
C2HCl3 + ·Cl → CHCl2C(·)Cl2
Reaction order:
2
Reference reaction:
C2H6 + ·Cl → ·C2H5 + HCl
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
7.21x10-11 [±7.97x10-12 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
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