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Author(s):   Vedeneev, V.I.; Teitel'boim, M.A.; Shoikhet, A.A.
Title:   The photolysis of CF3I in the presence of O2 and Br2. 2. Determination of rate constants for the reactions of CF3 radicals with O2 and F2
Journal:   Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Year:   1979
Reference type:   Journal article
Squib:   1979VED/TEI2475

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1979VED/TEI2475   ·CF3 + F2CF4 + ·F  253 - 343   3.01E-12       1.21E04   2.24E-14  2
  1979VED/TEI2475   ·CF3 + O2CF3O2  253 - 343   4.90E-12       2844   1.55E-12  2
  1979VED/TEI2475   ·CF3 + O2CF3O2  253 - 343   1.12       -2420   2.97  2
  Reference reaction:  ·CF3 + Br2CF3Br + Br· 2

Search returned 3 records.