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Title: Die kinetik und der mechanismus der photochemischen reaktion zwischen F2O und SF4 bei 365 nm
Journal: J. Photochem.
Volume: 20
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982GON/SCH85
Reaction:
OF2 + SF5 → SF6 + OF
Reaction order:
2
Temperature:
313 - 338
K
Pressure: 0.22 - 0.75 bar
Rate expression:
2.71x10-12 [±2.49x10-13 cm3/molecule s] e-42653 [±6402 J/mole]/RT
Bath gas:
OF2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 313 | 2.06E-19 |
| 325 | 3.78E-19 |
| 338 | 6.93E-19 |