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Author(s):   Gonzalez, A.C.; Schumacher, H.J.
Title:   Die kinetik und der mechanismus der photochemischen reaktion zwischen F2O und SF4 bei 365 nm
Journal:   J. Photochem.
Volume:   20
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982GON/SCH85

Reaction:   OF2 + SF5SF6 + OF
Reaction order:   2
Temperature:   313 - 338 K
Pressure:  0.22 - 0.75 bar
Rate expression:   2.71x10-12 [±2.49x10-13 cm3/molecule s] e-42653 [±6402 J/mole]/RT
Bath gas:   OF2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Pressure measurement

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
313 2.06E-19
325 3.78E-19
338 6.93E-19