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Accessibility information
Author(s):   Fontijn, A.; Felder, W.
Title:   HTFFR kinetics studies of Al + CO2 →’ AlO + CO from 300 to 1900 K, a non-arrhenius reaction
Journal:   J. Chem. Phys.
Volume:   67
Year:   1977
Reference type:   Journal article
Squib:   1977FON/FEL1561

Reaction:   CO2 + AlCO + AlO
Reaction order:   2
Temperature:   1500 - 1880 K
Pressure:  4.00E-3 - 4.27E-2 bar
Rate expression:   1.12x10-8 [cm3/molecule s] e-88965 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1500 8.95E-12
1525 1.01E-11
1550 1.13E-11
1575 1.26E-11
1600 1.40E-11
1625 1.55E-11
1650 1.71E-11
1675 1.88E-11
1700 2.07E-11
1725 2.27E-11
1750 2.48E-11
1775 2.70E-11
1800 2.94E-11
1825 3.19E-11
1850 3.45E-11
1875 3.73E-11
1880 3.78E-11