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Accessibility information
Author(s):   Garland, N.L.
Title:   Kinetic studies of boron and aluminum species
Page(s):   73 - 91
Year:   1992
Book Title:   Gas-Phase Metal Reactions
Publisher address:   ed. A. Fontijn, pub. Elsevier Science Publ., Amsterdam, Netherlands
Reference type:   Book Chapter
Squib:   1992GAR73-91C

Reaction:   CO2 + AlCO + AlO
Reaction order:   2
Temperature:   750 - 1200 K
Pressure:  2.67E-2 - 0.40 bar
Rate expression:   2.91x10-10 [±6.97x10-11 cm3/molecule s] e-26773 [±1605 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
750 3.97E-12
775 4.56E-12
800 5.19E-12
825 5.86E-12
850 6.58E-12
875 7.33E-12
900 8.12E-12
925 8.94E-12
950 9.80E-12
975 1.07E-11
1000 1.16E-11
1025 1.26E-11
1050 1.35E-11
1075 1.45E-11
1100 1.56E-11
1125 1.66E-11
1150 1.77E-11
1175 1.88E-11
1200 1.99E-11