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Chemical Sciences Division
Honma, K.; Hirata, D.|
Reaction dynamics of Al + CO2 -> AlO plus CO studied by a crossed-beam velocity map imaging technique
J. Chem. Phys.
CO2 + Al → CO + AlO
no rate data available
Mechanistic information only
Flash photolysis (laser or conventional)
By end product analysis
The oxidation reaction of a gas-phase aluminum atom by a carbon dioxide molecule was studied by employing a crossed-beam technique at two collision energies: 27.9 and 52.8 kJ/mol. The results suggested that the reaction proceeds via a short-lived intermediate in which the O–C–O keeps a nearly linear structure.
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