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Author(s):   Bourbon, C.; Fittschen, C.; Sawerysyn, J.P.; Devolder, P.
Title:   Temperature dependence of the gas phase reaction rates of CF3O with methane, ethane, and isobutane
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   15102 - 15107
Year:   1995
Reference type:   Journal article
Squib:   1995BOU/FIT15102-15107

Reaction:   CH4 + CF3O → CF3OH + ·CH3
Reaction order:   2
Temperature:   296 - 573 K
Pressure:  1.33E-3 bar
Rate expression:   4.48x10-12 [±1.39x10-12 cm3/molecule s] e-13386 [±668 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 1.95E-14
300 2.09E-14
325 3.16E-14
350 4.51E-14
375 6.12E-14
400 8.01E-14
425 1.01E-13
450 1.25E-13
475 1.51E-13
500 1.79E-13
525 2.09E-13
550 2.40E-13
573 2.70E-13