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Title: Temperature dependence of the gas phase reaction rates of CF3O with methane, ethane, and isobutane
Journal: J. Phys. Chem.
Volume: 99
Page(s): 15102 - 15107
Year: 1995
Reference type: Journal article
Squib: 1995BOU/FIT15102-15107
Reaction:
CH4 + CF3O → CF3OH + ·CH3
Reaction order:
2
Temperature:
296 - 573
K
Pressure: 1.33E-3 bar
Rate expression:
4.48x10-12 [±1.39x10-12 cm3/molecule s] e-13386 [±668 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 296 | 1.95E-14 |
| 300 | 2.09E-14 |
| 325 | 3.16E-14 |
| 350 | 4.51E-14 |
| 375 | 6.12E-14 |
| 400 | 8.01E-14 |
| 425 | 1.01E-13 |
| 450 | 1.25E-13 |
| 475 | 1.51E-13 |
| 500 | 1.79E-13 |
| 525 | 2.09E-13 |
| 550 | 2.40E-13 |
| 573 | 2.70E-13 |