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Accessibility information
Author(s):   Seetula, J.A.
Title:   Kinetics of the R+Cl2, (R = CH2Cl, CHBrCl, CCl3 and CH3CCl2) reactions. An ab initio study of the transition states
Journal:   J. Chem. Soc. Farad. Trans.
Volume:   94
Page(s):   3561 - 3567
Year:   1998
Reference type:   Journal article
Squib:   1998SEE3561-3567

Reaction:   Cl2 + CH3CCl2· → CH3CCl3 + ·Cl
Reaction order:   2
Temperature:   414 - 873 K
Pressure:  5.84E11 - 1.19E12 bar
Rate expression:   4.79x10-16 [±4.36x10-18 cm3/molecule s] (T/298 K)4.30 e15000 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   GC-MS

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
414 1.54E-13
425 1.54E-13
450 1.55E-13
475 1.59E-13
500 1.64E-13
525 1.70E-13
550 1.78E-13
575 1.86E-13
600 1.96E-13
625 2.08E-13
650 2.20E-13
675 2.33E-13
700 2.48E-13
725 2.64E-13
750 2.81E-13
775 2.99E-13
800 3.19E-13
825 3.40E-13
850 3.63E-13
873 3.85E-13