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 Author(s):   Ignatov, S.K.; Sennikov, P.G.; Razuvaev, A.G.; Chuprov, L.A.; Schrem. O.; Ault, B.S.
Title:   Theoretical Study of the Reaction Mechanism and Role of Water Clusters in the Gas-Phase Hydrolysis of SiCl4
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   8705 - 8713
Year:   2003
Reference type:   Journal article
Squib:   2003IGN/SEN8705-8713

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2003IGN/SEN8705-8713   H2O + SiCl4 → HCl + SiCl3OH                     2
    2003IGN/SEN8705-8713   H2O + SiCl3OH → SiCl2(OH)2 + HCl                     2
    2003IGN/SEN8705-8713   SiCl2(OH)2 + H2O → SiCl(OH)3 + HCl                     2
    2003IGN/SEN8705-8713   SiCl(OH)3 + H2O → Si(OH)4 + HCl                     2
    2003IGN/SEN8705-8713   SiCl4 + SiCl3OH → HCl + SiCl3OSiCl3                     2
    2003IGN/SEN8705-8713   SiCl3OH + SiCl3OH → H2O + SiCl3OSiCl3                     2
    2003IGN/SEN8705-8713   SiCl2(OH)2 + SiCl2(OH)2 → SiCl2(OH)OSiCl2(OH) + H2O                     2
    2003IGN/SEN8705-8713   SiCl(OH)3 + SiCl(OH)3 → SiCl(OH)2OSiCl(OH)2 + H2O                     2
    2003IGN/SEN8705-8713   Si(OH)4 + Si(OH)4 → Si(OH)3OSi(OH)3 + H2O                     2
    2003IGN/SEN8705-8713   H2O + H2O + SiCl4 → HCl + H2O + SiCl3OH  270 - 1200               0.00E00  3
    2003IGN/SEN8705-8713   H2O + H2O + H2O + SiCl4 → HCl + H2O + H2O + SiCl3OH  270 - 1200               0.00E00   
Search returned 11 records.