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Author(s):   Maricq, M.M.; Szente, J.J.
Title:   Upper limits for the rate constants of the reactions CF3O+O3→’CF3O2+O2 and CF3O2+O3→’CF3O+2O2
Journal:   Chem. Phys. Lett.
Volume:   213
Page(s):   449 - 456
Year:   1993
Reference type:   Journal article
Squib:   1993MAR/SZE449-456

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993MAR/SZE449-456   CHF3 + ·F → ·CF3 + HF  210 - 353   3.60E-12       7899   1.49E-13  2
  1993MAR/SZE449-456   O3 + CF3O2 → O2 + O2 + CF3O  210 - 353   <1.00E-14           1.00E-14  2
  1993MAR/SZE449-456   O3 + CF3O → O2 + CF3O2  210 - 353   <5.00E-14           5.00E-14  2
  1993MAR/SZE449-456   CF3O2 + CF3O2 → O2 + CF3O + CF3O  210 - 353   1.50E-12       -1663   2.94E-12  2
Search returned 4 records.