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Author(s):   Brown, T.C.; King, K.D.; Nguyen, T.T.
Title:   Kinetics of primary processes in the pyrolysis of cyclopentanes and cyclohexanes
Journal:   J. Phys. Chem.
Volume:   90
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986BRO/KIN419

Reaction:   Cyclopentane → Products
Reaction order:   1
Temperature:   900 - 1220 K
Rate expression:   6.31x1016 [s-1] e-355028 [±7101 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Cyclopentane
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 1.57E-4
925 5.65E-4
950 1.90E-3
975 6.03E-3
1000 1.80E-2
1025 5.10E-2
1050 1.38E-1
1075 3.54E-1
1100 8.74E-1
1125 2.07E0
1150 4.73E0
1175 1.04E1
1200 2.22E1
1220 3.98E1