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Accessibility information
Author(s):   Abell, P.I.
Title:   Relative reactivity of olefins to HBr in the gas phase
Journal:   Trans. Faraday Soc.
Volume:   60
Page(s):   2214 - 2223
Year:   1964
Reference type:   Journal article
Squib:   1964ABE2214-2223

Reaction:   CH3CH=CHCH3 + HBrsec-C4H9Br
Reaction order:   2
Reference reaction:   C2H4 + HBrC2H5Br
Reference reaction order:   2
Temperature:   313 - 393 K
Pressure:  4.00E-2 - 0.15 bar
Rate expression:   1.5x10-1 e160469 [J/mole]/RT
Bath gas:   HBr
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
313 9.02E25
325 9.26E24
350 1.33E23
375 3.37E21
393 3.19E20