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Title: Relative reactivity of olefins to HBr in the gas phase
Journal: Trans. Faraday Soc.
Volume: 60
Page(s): 2214 - 2223
Year: 1964
Reference type: Journal article
Squib: 1964ABE2214-2223
Reaction:
CH3CH=CHCH3 + HBr → sec-C4H9Br
Reaction order:
2
Reference reaction:
C2H4 + HBr → C2H5Br
Reference reaction order:
2
Temperature:
313 - 393
K
Pressure: 4.00E-2 - 0.15 bar
Rate expression:
1.5x10-1 e160469 [J/mole]/RT
Bath gas:
HBr
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 313 | 9.02E25 |
| 325 | 9.26E24 |
| 350 | 1.33E23 |
| 375 | 3.37E21 |
| 393 | 3.19E20 |