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Author(s):   Kambanis, K.G.; Lazarou, Y.G.; Papagiannakopoulos, P.
Title:   Kinetic studies of the reaction of Cl atoms with CH3SSCH3
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   92
Page(s):   4905 - 4908
Year:   1996
Reference type:   Journal article
Squib:   1996KAM/LAZ4905-4908

Reaction:   (CH3S)2 + ·ClHCl + CH3SSCH2
Reaction order:   2
Temperature:   273 - 363 K
Rate expression:   1.83x10-10 [±7.31x10-12 cm3/molecule s] e-2428 [±219 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 6.27E-11
275 6.32E-11
300 6.90E-11
325 7.44E-11
350 7.93E-11
363 8.17E-11