Author(s):   Dibble, T.S.; Sha, Y.; Thornton, W.F.; Zhang, F.
Title:   Cis-Trans Isomerization of Chemically Activated 1-Methylallyl Radical and Fate of the Resulting 2-Buten-1-peroxy Radical
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   7603 - 7614
Year:   2012
Reference type:   Journal article
Squib:   2012DIB/SHA7603-7614

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	k(298.00 K)	Order
2012DIB/SHA7603-7614	(E)-2-C₄H₈ + ·OH → H₂O + (E)-CH₃CH=CHCH₂	300 - 700		2
Reference reaction: (E)-2-C₄H₈ + ·OH → H₂O + (Z)-CH₃CH=CHCH₂·			2
2012DIB/SHA7603-7614	(E)-CH₃CH=CHCH₂ → (Z)-CH₃CH=CHCH₂·	500 - 1100		1
2012DIB/SHA7603-7614	trans-CH₃CH=CHCH₂OO· → Products			1
2012DIB/SHA7603-7614	cis-CH₃CH=CHCH₂OO· → Products			1

Search returned 4 records.