 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: The thermal unimolecular isomerization and decomposition
Journal: J. Chem. Soc.
Page(s): 191 - 194
Year: 1965
Reference type: Journal article
Squib: 1965FRE/MAR191-194
Reaction:
Cyclopropane, 1,1-diethyl- → (C2H5)2C=CHCH3
Reaction order:
1
Temperature:
698 - 748
K
Pressure: 1.33E-3 - 2.13E-2 bar
Rate expression:
6.92x1014 [s-1] e-265232 [J/mole]/RT
Bath gas:
Cyclopropane, 1,1-diethyl-
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 698 | 9.82E-6 |
| 700 | 1.12E-5 |
| 725 | 5.38E-5 |
| 748 | 2.08E-4 |