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Title: Are reaction rate coefficients additive? Revised transition state theory calculations for OH + alkane reactions
Journal: Int. J. Chem. Kinet.
Volume: 23
Page(s): 397 - 417
Year: 1991
Reference type: Journal article
Squib: 1991COH397-417
Reaction:
(CH3)3CCH2CH3 + ·OH → H2O + (CH3)3CCH2CH2·
Reaction order:
2
Temperature:
298 - 500
K
Rate expression:
4.52x10-13 [cm3/molecule s] (T/298 K)1.80 e-4074 [J/mole]/RT
Category: Theory
Data type:
Transition state theory
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 8.72E-14 |
| 300 | 8.93E-14 |
| 325 | 1.17E-13 |
| 350 | 1.49E-13 |
| 375 | 1.85E-13 |
| 400 | 2.25E-13 |
| 425 | 2.70E-13 |
| 450 | 3.19E-13 |
| 475 | 3.73E-13 |
| 500 | 4.30E-13 |