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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Bromination of fluoroalkanes. Part 4.-Kinetics of thermal bromination of fluoroform and pentafluorethane
Journal:   Trans. Faraday Soc.
Volume:   64
Page(s):  
Year:   1968
Reference type:   Journal article
Squib:   1968AMP/WHI2130

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1968AMP/WHI2130   CH3OH + Br·(·)CH2OH + HBr  340 - 367   5.25E-12       3.13E04      2
  1968AMP/WHI2130   CHCl3 + Br··CCl3 + HBr  420 - 455   3.80E-12       3.89E04      2
  1968AMP/WHI2130   CH4 + Br··CH3 + HBr  634 - 704   1.63E-10       7.77E04      2
  1968AMP/WHI2130   CH3Br + Br·HBr + ·CH2Br  596 - 731   1.66E-10       6.83E04      2
  1968AMP/WHI2130   C2H6 + Br··C2H5 + HBr  312 - 483   2.26E-10       5.73E04      2
  1968AMP/WHI2130   CH3Cl + Br··CH2Cl + HBr  423 - 483   1.19E-10       6.16E04      2
  1968AMP/WHI2130   C3H8 + Br·2-C3H7 + HBr  423 - 483   1.51E-10       4.36E04      2
  1968AMP/WHI2130   CH2F2 + Br··CHF2 + HBr  398 - 573   3.95E-11       6.93E04      2
  1968AMP/WHI2130   iso-C4H10 + Br·tert-C4H9 + HBr  423 - 483   6.33E-11       3.25E04      2
  1968AMP/WHI2130   CH3CHF2 + Br·HBr + CH3CF2  298 - 389   3.82E-11       6.04E04   9.70E-22  2
  1968AMP/WHI2130   CHF3 + Br··CF3 + HBr  634 - 704   2.16E-11       9.31E04      2
  1968AMP/WHI2130   CCl3Br + Br··CCl3 + Br2  420 - 455   1.35E-10       4.27E04      2
  1968AMP/WHI2130   CF3Br + Br··CF3 + Br2  350 - 600   1.05E-10       1.01E05      2
  1968AMP/WHI2130   CF3CHO + Br·CF3C(O) + HBr  300 - 400   4.65E-12       2.76E04      2
  1968AMP/WHI2130   1-C4H10 + Br·sec-C4H9 + HBr  423 - 483   4.78E-10       4.39E04      2
  1968AMP/WHI2130   C2H5F + Br·HBr + CH3C(·)HF  312 - 394   2.19E-11       4.85E04      2
  1968AMP/WHI2130   C2F5H + Br·C2F5 + HBr  596 - 731   1.83E-11       8.07E04      2
  1968AMP/WHI2130   CHF2CHF2 + Br·HBr + CHF2CF2  391 - 556   6.63E-11       8.10E04      2
  1968AMP/WHI2130   CH3CF3 + Br·CF3CH2 + HBr  516 - 652   1.71E-10       9.81E04      2
  1968AMP/WHI2130   neo-C5H12 + Br·Neopentyl + HBr  423 - 483   5.06E-10       6.05E04      2
  1968AMP/WHI2130   CH3F + Br··CH2F + HBr  396 - 581   9.05E-11       6.73E04      2
  1968AMP/WHI2130   CF3CH2F + Br·HBr + CF3CHF  403 - 591   6.41E-11       8.16E04      2
  1968AMP/WHI2130   H2 + Br·HBr +   300 - 1400   4.47E-10       8.24E04      2
  1968AMP/WHI2130   C2F5CF2H + Br·n-C3F7 + HBr  526 - 675   1.48E-11       7.98E04      2
  1968AMP/WHI2130   ·CF3 + HBrCHF3 + Br·  634 - 704   0.26       8896      2
  Reference reaction:  ·CF3 + Br2CF3Br + Br· 2
  1968AMP/WHI2130   C2F5 + HBrC2F5H + Br·  596 - 731   0.35       1.15E04      2
  Reference reaction:  C2F5 + Br2C2F5Br + Br· 2
  1968AMP/WHI2130   D2 + Br·DBr + D  300 - 1400   3.24E-10       8.98E04      2

Search returned 27 records.