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Title: Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal: J. Chem. Soc. A
Page(s):
Year: 1967
Reference type: Journal article
Squib: 1967DIJ/KER105
Reaction:
CH3CHCH2NF2 → CH3CH=CH2 + NF2
Reaction order:
1
Reference reaction:
NF2 + CH3CHCH2NF2 → Propane, 1,2-(difluoroamino)-
Reference reaction order:
2
Temperature:
334 - 428
K
Rate expression:
6.02x1020 [molecule/cm3] e-56455 [J/mole]/RT
Bath gas:
N2F4
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [molecule/cm3] |
|---|---|
| 334 | 8.93E11 |
| 350 | 2.26E12 |
| 375 | 8.24E12 |
| 400 | 2.56E13 |
| 425 | 6.94E13 |
| 428 | 7.76E13 |