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Author(s):   Dijkstra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal:   J. Chem. Soc. A
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER105

Reaction:   Cyclopentyl, 2-(difluoroamino)- → Cyclopentene + NF2
Reaction order:   1
Reference reaction:   NF2 + Cyclopentyl, 2-(difluoroamino)- → 1,2-Cyclopentanediamino, N,N,N',N'-tetrafluoro-
Reference reaction order:   2
Temperature:   334 - 391 K
Rate expression:   6.02x1021 [molecule/cm3] e-40990 [J/mole]/RT
Bath gas:   N2F4
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
334 2.34E15
350 4.60E15
375 1.18E16
391 2.01E16