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Title: Elimination kinetics and mechanisms for several 2-alkoxyacetic acids in the gas phase
Journal: J. Phys. Org. Chem.
Volume: 9
Page(s): 787 - 794
Year: 1996
Reference type: Journal article
Squib: 1996CHU/ROT787-794
Reaction:
C2H5OCH2COOH → CH2O + C2H5OH + CO
Reaction order:
1
Temperature:
379 - 410
K
Pressure: 7.60E-2 - 0.35 bar
Rate expression:
5.75x1012 [s-1] e-199547 [±3991 J/mole]/RT
Uncertainty:
1.95000005
Bath gas:
Cyclohexene
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 379 | 1.81E-15 |
| 400 | 5.03E-14 |
| 410 | 2.18E-13 |