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Author(s):   Sharma, H.D.; Sood, S.P.
Title:   Isotopic exchange reactions between nitrogen oxides and oxyhalides
Journal:   J. Phys. Chem.
Volume:   78
Page(s):   402 - 405
Year:   1974
Reference type:   Journal article
Squib:   1974SHA/SOO402-405

Reaction:   NOCl + NO2NO + ClNO2
Reaction order:   2
Temperature:   273 - 296 K
Pressure:  1.83E-3 - 1.04E-2 bar
Rate expression:   2.96x10-16 [±5.98x10-18 cm3/molecule s] e-27853 [±1114 J/mole]/RT
Bath gas:   NOCl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 1.38E-21
275 1.51E-21
296 3.59E-21