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Accessibility information
Author(s):   Harris, G.W.; Pitts, J.N., Jr.
Title:   Absolute Rate Constants and Temperature Dependences for the Gas Phase Reactions of H Atoms with Propene and the Butenes in the Temperature Range 298 to 445 K
Journal:   J. Chem. Phys.
Volume:   77
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982HAR/PIT3994

Reaction:   1-C4H8 + → Products
Reaction order:   2
Temperature:   298 - 445 K
Pressure:  6.67E-2 bar
Rate expression:   3.77x10-11 [±4.15x10-12 cm3/molecule s] e-7832 [±783 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.60E-12
300 1.63E-12
325 2.08E-12
350 2.56E-12
375 3.06E-12
400 3.58E-12
425 4.11E-12
445 4.54E-12