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Accessibility information
Author(s):   Kakumoto, T.; Saito, K.; Imamura, A.
Title:   Unimolecular decomposition of oxalic acid
Journal:   J. Phys. Chem.
Volume:   91
Year:   1987
Reference type:   Journal article
Squib:   1987KAK/SAI2366

Reaction:   HOOCCOOHCO2 + CO + H2O
Reaction order:   1
Temperature:   300 - 1300 K
Rate expression:   7.94x1014 [s-1] e-124717 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Ab initio

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.53E-7
400 4.11E-2
500 7.43E1
600 1.10E4
700 3.92E5
800 5.71E6
900 4.59E7
1000 2.43E8
1100 9.50E8
1200 2.96E9
1300 7.74E9