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Title: Arrhenius Parameters for the Reactions of O(3P) Atoms with Several Aldehydes and the Trend in Aldehydic C-H Bond Dissociation Energies
Journal: Can. J. Chem.
Volume: 55
Page(s):
Year: 1977
Reference type: Journal article
Squib: 1977SIN/IRW3321
Reaction:
CH3CH2CH2CHO + O· → ·OH + CH3CH2CH2CO
Reaction order:
2
Temperature:
298 - 472
K
Pressure: 4.00E-2 - 8.00E-2 bar
Rate expression:
1.03x10-11 [±1.99x10-13 cm3/molecule s] e-5978 [±59.78 J/mole]/RT
Bath gas:
CH3CH2CH2CHO
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 9.25E-13 |
| 300 | 9.40E-13 |
| 325 | 1.13E-12 |
| 350 | 1.32E-12 |
| 375 | 1.52E-12 |
| 400 | 1.71E-12 |
| 425 | 1.90E-12 |
| 450 | 2.09E-12 |
| 472 | 2.25E-12 |