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Author(s):   Chakravarty, H. K.; Fernandes, R. X.
Title:   Reaction Kinetics of Hydrogen Abstraction Reactions by Hydroperoxyl Radical from 2-Methyltetrahydrofuran and 2,5-Dimethyltetrahydrofura
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   5028 - 5041
Year:   2013
Reference type:   Journal article
Squib:   2013CHA/FER5028-5041

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2013CHA/FER5028-5041   2-methyltetrahydrofuran + HO2 → (2-tetrahydrofuran)-methyl + H2O2  500 - 2000   1.06E-13   3.47   7.15E04      2
  2013CHA/FER5028-5041   2-methyltetrahydrofuran + HO2 → 2-methyl-tetrahydrofuran-2-yl + H2O2  500 - 2000   1.33E-14   3.27   2.68E04      2
  2013CHA/FER5028-5041   2-methyltetrahydrofuran + HO2 → 2-methyl-tetrahydrofuran-3-yl + H2O2  500 - 2000   3.13E-15   3.72   5.09E04      2
  2013CHA/FER5028-5041   2-methyltetrahydrofuran + HO2 → 2-methyl-tetrahydrofuran-4-yl + H2O2  500 - 2000   1.98E-15   4.13   4.79E04      2
  2013CHA/FER5028-5041   2-methyltetrahydrofuran + HO2 → 2-methyl-tetrahydrofuran-5-yl + H2O2  500 - 2000   7.01E-15   3.53   3.30E04      2
  2013CHA/FER5028-5041   2-methyltetrahydrofuran + HO2 → Other Products + H2O2  500 - 2000   1.54E-15   4.72   2.03E04      2
  2013CHA/FER5028-5041   2,5-Dimethyltetrahydrofuran + HO2 → Other Products + H2O2  500 - 2000   5.80E-15   4.71   1.62E04      2
  2013CHA/FER5028-5041   2,5-Dimethyltetrahydrofuran + HO2 → tetrahydro-5-methyl-2-furanylmethyl + H2O2  500 - 2000   5.71E-13   3.59   7.29E04      2
  2013CHA/FER5028-5041   2,5-Dimethyltetrahydrofuran + HO2 → tetrahydro-2,5-dimethyl-2-furanyl + H2O2  500 - 2000   1.07E-13   3.14   2.51E04      2
  2013CHA/FER5028-5041   2,5-Dimethyltetrahydrofuran + HO2 → tetrahydro-2,5-dimethyl-3-furanyl + H2O2  500 - 2000   3.80E-14   3.73   5.55E04      2
  2013CHA/FER5028-5041   Methylcyclopentane + HO2 → 1-methyl-cyclopentyl + H2O2  500 - 2000   3.56E-15   3.48   3.60E04      2
  2013CHA/FER5028-5041   Methylcyclopentane + HO2 → 2-methyl-cyclopentyl + H2O2  500 - 2000   4.98E-15   3.66   4.72E04      2
  2013CHA/FER5028-5041   Methylcyclopentane + HO2 → ·CH2-cyc-C5H9 + H2O2  500 - 2000   8.67E-14   3.51   6.55E04      2

Search returned 13 records.