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Author(s):   Eskola, A.J.; Golonka, I.; Rissanen, M.P.; Timonen, R.S.
Title:   Kinetics of the CCl2+Br2 and CCl2+NO2 reactions in the temperature range 266-365 K and reactivity of the CCl2 biradical
Journal:   Chem. Phys. Lett.
Volume:   460
Page(s):   401 - 405
Year:   2008
Reference type:   Journal article
Squib:   2008ESK/GOL401-405

Reaction:   CCl2 (X 1A1) + Cl2·CCl3 + ·Cl
Reaction order:   2
Temperature:   298 K
Pressure:  1.64E-20 bar
Rate expression:   6.4x10-12 [±2.0x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Mass spectrometry

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