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Author(s):   Davidson, I.M.T.; Barton, T.J.; Hughes, K.J.; Ijadi-Maghsoodi, S.; Revis, A.; Paul, G.C.
Title:   Kinetics of radical-forming homolyses in alkenyl- and tert-butyisilanes. The stability of α- and β-silicon-substituted alkyl radicals
Journal:   Organometallics
Volume:   6
Year:   1987
Reference type:   Journal article
Squib:   1987DAV/BAR644

Reaction:   (CH3)3CCH2CH3tert-C4H9 + ·C2H5
Reaction order:   1
Temperature:   723 - 985 K
Pressure:  1.33 bar
Rate expression:   1.26x1016 [s-1] e-320107 [±3201 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
723 9.42E-8
725 1.09E-7
750 6.41E-7
775 3.36E-6
800 1.58E-5
825 6.81E-5
850 2.69E-4
875 9.80E-4
900 3.33E-3
925 1.06E-2
950 3.16E-2
975 8.94E-2
985 1.33E-1