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Accessibility information
Author(s):   Hippler, H.; Reihs, C.; Troe, J.
Title:   Elementary steps in the pyrolysis of toluene and benzyl radicals
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   167
Page(s):   1 - 16
Year:   1990
Reference type:   Journal article
Squib:   1990HIP/REI1-16

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990HIP/REI1-16   Toluene → Products  1200 - 1500   1.00E15       3.60E05      1
  1990HIP/REI1-16   Toluene → Benzyl + H·  1100 - 1900   6.31E15       3.78E05      1
  1990HIP/REI1-16   Toluene + H· → H2 + Benzyl  600 - 1800   2.09E-10       3.50E04      2
  1990HIP/REI1-16   Benzyl → Products  1700 - 1900   2.00E15       3.50E05      1
Search returned 4 records.