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Author(s):   Fenske, J.D.; Hasson, A.S.; Ho, A.W.; Paulson, S.E.
Title:   Measurement of Absolute Unimolecular and Bimolecular Rate Constants for CH3CHOO Generated by the trans-2-Butene Reaction with Ozone in the Gas Phase
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   9921 - 9932
Year:   2000
Reference type:   Journal article
Squib:   2000FEN/HAS9921-9932

Reaction:   (E)-2-C4H8 + O3 → Other Products + CH3CHO
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.9x10-16 [±3.0x10-17 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Flow tube - Data taken vs distance
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Reaction monitored by following acetaldehyde product.
Atmospheric pressure flow reactor; T and P not specified.

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