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Accessibility information
Author(s):   Buxton, J.P.; Simpson, C.J.S.M.
Title:   Thermal decarbonylations of unsaturated cyclic ketones: Kinetics and dynamics
Journal:   Chem. Phys.
Volume:   105
Year:   1986
Reference type:   Journal article
Squib:   1986BUX/SIM307

Reaction:   3,5-CycloheptadienoneCO + (E)-CH2=CHCH=CHCH=CH2
Reaction order:   1
Temperature:   1070 - 1220 K
Pressure:  0.82 bar
Rate expression:   7.94x1013 [s-1] e-207030 [±10310 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1070 6.21E3
1075 6.92E3
1100 1.17E4
1125 1.94E4
1150 3.14E4
1175 4.97E4
1200 7.73E4
1220 1.09E5