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Accessibility information
Author(s):   Buxton, J.P.; Simpson, C.J.S.M.
Title:   Thermal decarbonylations of unsaturated cyclic ketones: Kinetics and dynamics
Journal:   Chem. Phys.
Volume:   105
Year:   1986
Reference type:   Journal article
Squib:   1986BUX/SIM307

Reaction:   3,5-CycloheptadienoneCO + (E)-CH2=CHCH=CHCH=CH2
Reaction order:   1
Temperature:   1140 - 1170 K
Pressure:  6.27E-3 - 0.82 bar
Rate expression:   1.58x1016 [s-1] e-255254 [±10227 J/mole]/RT
Uncertainty:   5.0
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1140 3.19E4
1150 4.03E4
1170 6.35E4