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Title: Mercury-photosensitized decomposition of aliphatic hydrocarbons-radical detection with ethyl-carbon-14 radicals
Journal: J. Phys. Chem.
Volume: 67
Page(s):
Year: 1963
Reference type: Journal article
Squib: 1963HOL/KLE2273
Reaction:
(CH3)3CCH2CH3 + H· → Other Products + H2
Reaction order:
2
Reference reaction:
C2H4 + H· → ·C2H5
Reference reaction order:
2
Temperature:
298
K
Pressure: 7.33E-2 - 0.57 bar
Rate expression:
1.8x10-3
Bath gas:
(CH3)3CCH2CH3
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Sensitized photolysis
Analytical technique:
Gas chromatography
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