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Author(s):   Fettis, G.C.; Knox, J.H.; Trotman-Dickenson, A.F.
Title:   The reactions of fluorine atoms with alkanes
Journal:   J. Chem. Soc.
Page(s):  
Year:   1960
Reference type:   Journal article
Squib:   1960FET/KNO1064

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1960FET/KNO1064   CH4 + ·F·CH3 + HF  198 - 351   1.63E-10       5055   2.11E-11  2
  1960FET/KNO1064   C2H6 + ·F·C2H5 + HF  198 - 351   7.90E-11       1164   4.94E-11  2
  1960FET/KNO1064   C2H6 + ·F·C2H5 + HF  198 - 351   0.38       -3875   1.82  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1960FET/KNO1064   C2H6 + ·F·C2H5 + HF  213 - 293   1.84       1164      2
  Reference reaction:  C3H8 + ·F1-C3H7 + HF 2
  1960FET/KNO1064   C3H8 + ·F2-C3H7 + HF  213 - 293   0.45              2
  Reference reaction:  Cyclopropane + ·FCyclopropyl + HF 2
  1960FET/KNO1064   C3H8 + ·F2-C3H7 + HF  213 - 293   6.81E-11              2
  1960FET/KNO1064   C3H8 + ·F2-C3H7 + HF  213 - 293   0.56              2
  Reference reaction:  1-C4H10 + ·Fsec-C4H9 + HF 2
  1960FET/KNO1064   C3H8 + ·F1-C3H7 + HF  213 - 293   5.81E-11              2
  1960FET/KNO1064   C3H8 + ·F1-C3H7 + HF  174 - 309   2.48           2.48  2
  Reference reaction:  C3H8 + ·F2-C3H7 + HF 2
  1960FET/KNO1064   C3H8 + ·F1-C3H7 + HF  213 - 293   1.13              2
  Reference reaction:  Cyclopropane + ·FCyclopropyl + HF 2
  1960FET/KNO1064   C3H8 + ·F1-C3H7 + HF  213 - 293   1.11              2
  Reference reaction:  1-C4H10 + ·F1-C4H9 + HF 2
  1960FET/KNO1064   Cyclopropane + ·FCyclopropyl + HF  213 - 293   3.87E-11              2
  1960FET/KNO1064   iso-C4H10 + ·Ftert-C4H9 + HF  213 - 293   9.55E-11              2
  1960FET/KNO1064   iso-C4H10 + ·Fiso-C4H9 + HF  213 - 293   6.41              2
  Reference reaction:  iso-C4H10 + ·Ftert-C4H9 + HF 2
  1960FET/KNO1064   iso-C4H10 + ·Fiso-C4H9 + HF  213 - 293   6.76E-11              2
  1960FET/KNO1064   iso-C4H10 + ·Fiso-C4H9 + HF  213 - 293   1.57              2
  Reference reaction:  1-C4H10 + ·F1-C4H9 + HF 2
  1960FET/KNO1064   1-C4H10 + ·Fsec-C4H9 + HF  213 - 293   7.77E-11              2
  1960FET/KNO1064   1-C4H10 + ·Fsec-C4H9 + HF  213 - 293   0.80              2
  Reference reaction:  Cyclopropane + ·FCyclopropyl + HF 2
  1960FET/KNO1064   1-C4H10 + ·F1-C4H9 + HF  213 - 293   6.46E-11              2
  1960FET/KNO1064   1-C4H10 + ·F1-C4H9 + HF  213 - 293   1.02              2
  Reference reaction:  Cyclopropane + ·FCyclopropyl + HF 2
  1960FET/KNO1064   1-C4H10 + ·F1-C4H9 + HF  213 - 293   1.30              2
  Reference reaction:  1-C4H10 + ·Fsec-C4H9 + HF 2
  1960FET/KNO1064   neo-C5H12 + ·FNeopentyl + HF  213 - 293   7.57E-11              2
  1960FET/KNO1064   neo-C5H12 + ·FNeopentyl + HF  213 - 293   1.22              2
  Reference reaction:  iso-C4H10 + ·Fiso-C4H9 + HF 2

Search returned 23 records.