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Author(s):   Husain, D.; Marshall, P.
Title:   Kinetic study of the absolute rate constant for the reaction between Na + N2O in the temperature range 349-917K by time-resolved atomic resonance absorption spectroscopy at λ = 589 nm (Na(32PJ) → Na(32S1/2)) following pulsed irradiation
Journal:   Combust. Flame
Volume:   60
Page(s):  
Year:   1985
Reference type:   Journal article
Squib:   1985HUS/MAR81

Reaction:   Na + N2ON2 + NaO
Reaction order:   2
Temperature:   349 - 917 K
Pressure:  4.67E-2 bar
Rate expression:   1.91x10-10 [±2.99x10-11 cm3/molecule s] e-12472 [±625 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
349 2.60E-12
350 2.63E-12
400 4.49E-12
450 6.81E-12
500 9.51E-12
550 1.25E-11
600 1.57E-11
650 1.90E-11
700 2.24E-11
750 2.58E-11
800 2.93E-11
850 3.27E-11
900 3.61E-11
917 3.72E-11