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Author(s):   Sidebottom, H.W.; Tedder, J.M.; Walton, J.C.
Title:   Free radical addition to olefins. Part 6.-Addition of sulphur chloride pentafluoride to fluoro-olefins
Journal:   Trans. Faraday Soc.
Volume:   66
Page(s):  
Year:   1970
Reference type:   Journal article
Squib:   1970SID/TED2038

Reaction:   SF5CH2CF2· → CH2=CF2 + SF5
Reaction order:   1
Reference reaction:   SF5CH2CF2· + SF5ClSF5 + SF5CH2CF2Cl
Reference reaction order:   2
Temperature:   313 - 418 K
Rate expression:   1.9x1037 [molecule/cm3] e-53129 [±4249 J/mole]/RT
Uncertainty:   3.1600000858306885
Bath gas:   SF5Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
313 2.59E28
325 5.50E28
350 2.24E29
375 7.57E29
400 2.20E30
418 4.37E30