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Accessibility information
Author(s):   Santioste Bermejo, Y.M.
Title:   Heavy atom kinetic isotope effects in the gas phase pyrolysis of β-propiolactone
Journal:   Afinidad
Volume:   44
Year:   1987
Reference type:   Journal article
Squib:   1987SAN424

Reaction:   2-OxetanoneC2H4 + CO2
Reaction order:   1
Temperature:   503 - 592 K
Pressure:  4.00E-2 - 0.36 bar
Rate expression:   2.07x1012 [s-1] e-153818 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
503 2.20E-4
525 1.03E-3
550 5.10E-3
575 2.20E-2
592 5.55E-2