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Author(s):   Garib, A.;Timerghazin, O.K.;Ariya, P.A.
Title:   Chlorine atom initiated reactions of selected tropospheric halocarbons - Kinetic and product studies
Journal:   Can. J. Chem.
Volume:   84
Page(s):   1686 - 1695
Year:   2006
Reference type:   Journal article
Squib:   2006GAR/TIM1686-1695

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006GAR/TIM1686-1695   CH2Br2 + ·Cl → Products  298   4.25           4.25  2
  Reference reaction:  CH4 + ·Cl → Products 2
  2006GAR/TIM1686-1695   CHClBr2 + ·Cl → Products  298   2.03           2.03  2
  Reference reaction:  CH4 + ·Cl → Products 2
  2006GAR/TIM1686-1695   CHBr3 + ·Cl → Products  298   2.81           2.81  2
  Reference reaction:  CH4 + ·Cl → Products 2
  2006GAR/TIM1686-1695   CH2Br2 + ·Cl → Products  298   4.25E-13           4.25E-13  2
  2006GAR/TIM1686-1695   CHClBr2 + ·Cl → Products  298   2.03E-13           2.03E-13  2
  2006GAR/TIM1686-1695   CHBr3 + ·Cl → Products  298   2.81E-13           2.81E-13  2
  2006GAR/TIM1686-1695   CH2=CCl2 + ·Cl → Products  298 - 358   1.10E-11       6302   8.64E-13  2
  2006GAR/TIM1686-1695   (Z)-CHCl=CHCl + ·Cl → Products  298 - 358   6.30E-12       6643   4.31E-13  2
  2006GAR/TIM1686-1695   (E)-CHCl=CHCl + ·Cl → Products  298 - 358   2.40E-12       8464   7.88E-14  2
  2006GAR/TIM1686-1695   C2HCl3 + ·Cl → Products  298 - 358   4.60E-12       7034   2.69E-13  2

Search returned 10 records.