Author(s):   Garib, A.;Timerghazin, O.K.;Ariya, P.A.
Title:   Chlorine atom initiated reactions of selected tropospheric halocarbons - Kinetic and product studies
Journal:   Can. J. Chem.
Volume:   84
Page(s):   1686 - 1695
Year:   2006
Reference type:   Journal article
Squib:   2006GAR/TIM1686-1695

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
2006GAR/TIM1686-1695	CH₂Br₂ + ·Cl → Products	298	4.25		4.25	2
Reference reaction: CH₄ + ·Cl → Products					2
2006GAR/TIM1686-1695	CHClBr₂ + ·Cl → Products	298	2.03		2.03	2
Reference reaction: CH₄ + ·Cl → Products					2
2006GAR/TIM1686-1695	CHBr₃ + ·Cl → Products	298	2.81		2.81	2
Reference reaction: CH₄ + ·Cl → Products					2
2006GAR/TIM1686-1695	CH₂Br₂ + ·Cl → Products	298	4.25E-13		4.25E-13	2
2006GAR/TIM1686-1695	CHClBr₂ + ·Cl → Products	298	2.03E-13		2.03E-13	2
2006GAR/TIM1686-1695	CHBr₃ + ·Cl → Products	298	2.81E-13		2.81E-13	2
2006GAR/TIM1686-1695	CH₂=CCl₂ + ·Cl → Products	298 - 358	1.10E-11	6302	8.64E-13	2
2006GAR/TIM1686-1695	(Z)-CHCl=CHCl + ·Cl → Products	298 - 358	6.30E-12	6643	4.31E-13	2
2006GAR/TIM1686-1695	(E)-CHCl=CHCl + ·Cl → Products	298 - 358	2.40E-12	8464	7.88E-14	2
2006GAR/TIM1686-1695	C₂HCl₃ + ·Cl → Products	298 - 358	4.60E-12	7034	2.69E-13	2

Search returned 10 records.