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 Author(s):   Moore, C.; Smith, I.W.M.
Title:   Rate constants for the reactions of fluorine atoms with alkanes and hydrofluorocarbons at room temperature
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   91
Page(s):   3041 - 3044
Year:   1995
Reference type:   Journal article
Squib:   1995MOO/SMI3041-3044

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995MOO/SMI3041-3044   CH4 + ·F → ·CH3 + HF  298   4.70E-11           4.70E-11  2
  1995MOO/SMI3041-3044   CH4 + ·F → ·CH3 + HF  298   6.70           6.70  2
  Reference reaction:  HCl + ·F → HF + ·Cl 2
  1995MOO/SMI3041-3044   C2H6 + ·F → ·C2H5 + HF  298   1.69E-10           1.69E-10  2
  1995MOO/SMI3041-3044   C2H6 + ·F → ·C2H5 + HF  298   3.10           3.10  2
  Reference reaction:  CH4 + ·F → ·CH3 + HF 2
  1995MOO/SMI3041-3044   CH2F2 + ·F → ·CHF2 + HF  298   0.16           0.16  2
  Reference reaction:  CH3F + ·F → ·CH2F + HF 2
  1995MOO/SMI3041-3044   CH2F2 + ·F → ·CHF2 + HF  298   4.70E-12           4.70E-12  2
  1995MOO/SMI3041-3044   CH2F2 + ·F → ·CHF2 + HF  298   0.67           0.67  2
  Reference reaction:  HCl + ·F → HF + ·Cl 2
  1995MOO/SMI3041-3044   CHF3 + ·F → ·CF3 + HF  298   1.35E-13           1.35E-13  2
  1995MOO/SMI3041-3044   CHF3 + ·F → ·CF3 + HF  298   0.02           0.02  2
  Reference reaction:  HCl + ·F → HF + ·Cl 2
  1995MOO/SMI3041-3044   C2F5H + ·F → C2F5 + HF  298   3.65E-13           3.65E-13  2
  1995MOO/SMI3041-3044   C2F5H + ·F → C2F5 + HF  298   2.60           2.60  2
  Reference reaction:  CHF3 + ·F → ·CF3 + HF 2
  1995MOO/SMI3041-3044   CH3CF3 + ·F → CF3CH2 + HF  298   2.09E-12           2.09E-12  2
  1995MOO/SMI3041-3044   CH3CF3 + ·F → CF3CH2 + HF  298   0.45           0.45  2
  Reference reaction:  CH2F2 + ·F → ·CHF2 + HF 2
  1995MOO/SMI3041-3044   CH3F + ·F → ·CH2F + HF  298   2.81E-11           2.81E-11  2
  1995MOO/SMI3041-3044   CH3F + ·F → ·CH2F + HF  298   4.00           4.00  2
  Reference reaction:  HCl + ·F → HF + ·Cl 2
  1995MOO/SMI3041-3044   CF3CH2F + ·F → HF + CF3CHF  298   1.25E-12           1.25E-12  2
  1995MOO/SMI3041-3044   CF3CH2F + ·F → HF + CF3CHF  298   0.27           0.27  2
  Reference reaction:  CH2F2 + ·F → ·CHF2 + HF 2
Search returned 17 records.