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Author(s):   Bogan, D.J.; Nesbitt, F.L.
Title:   Ethoxy radical yield in the system C2D5OH plus F(2P) plus F2 at P = 1 torr and T = 223-423 K
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   1151 - 1155
Year:   1994
Reference type:   Journal article
Squib:   1994BOG/NES1151-1155

Reaction:   C2D5OH + ·FHF + CD3CD2
Reaction order:   2
Reference reaction:   C2D5OH + ·F → Products
Reference reaction order:   2
Temperature:   223 - 423 K
Rate expression:   2.5x10-1 e1763 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
223 6.47E-1
225 6.41E-1
250 5.84E-1
275 5.40E-1
300 5.07E-1
325 4.80E-1
350 4.58E-1
375 4.40E-1
400 4.25E-1
423 4.13E-1