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Author(s):   Hoyermann, K.; Maarfeld, S.; Nacke, F.; Nothdurft, J.; Olzmann, M.; Wehmeyer, J.; Welz, O.; Zeuch, T.
Title:   Rate coefficients for cycloalkyl plus O reactions and product branching in the decomposition of chemically activated cycloalkoxy radicals: an experimental and theoretical study
Journal:   Phys. Chem. Chem. Phys.
Volume:   12
Page(s):   8954 - 8968
Year:   2010
Reference type:   Journal article
Squib:   2010HOY/MAA8954-8968

Reaction:   Cyclohexyl + Cyclohexanone +
Reaction order:   2
Reference reaction:   Cyclohexyl + → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  4.00E-3 - 1.00 bar
Rate expression:   2.4x10-1
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)

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