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Title: Rate coefficients for reactions of OH radicals with CH3D, CH2D2, CHD3, and CD4
Journal: Int. J. Chem. Kinet.
Volume: 51
Page(s): 390 - 394
Year: 2019
Reference type: Journal article
Squib: 2019FRE/AND390-394
Reaction:
CH2D2 + ·OH → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
4.11x10-15 [±7.4x10-16 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
1,1,1,2-Tetrafluoroethane and methane were used as reference compounds. Uncertainties include two standard deviations of the linear least squares analysis, a 5% uncertainty range associated with the FTIR analysis, as well as error propagation of the uncertainties of reference rate coefficients. The final quoted uncertainty encompasses the extremes of the individual determinations.
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