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Accessibility information
Author(s):   Wijnen, M.H.J.
Title:   The reaction of methyl radicals with aceto- and propio-nitrile
Journal:   J. Chem. Phys.
Volume:   22
Year:   1954
Reference type:   Journal article
Squib:   1954WIJ1074

Reaction:   CH3CN + CD3CHD3 + CH2CN
Reaction order:   2
Reference reaction:   (CD3)2CO + CD3 → Other Products + CD4
Reference reaction order:   2
Temperature:   373 - 563 K
Pressure:  6.00E-2 - 8.00E-2 bar
Rate expression:   1.08 e4132 [J/mole]/RT
Bath gas:   CH3CN
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
373 4.09E0
375 4.06E0
400 3.74E0
425 3.48E0
450 3.26E0
475 3.07E0
500 2.92E0
525 2.78E0
550 2.67E0
563 2.61E0